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The diffusion of ferrocene methanol in super-cooled aqueous solutions containing sucrose has been studied, using disk and cylindrical microelectrodes, over a wide viscosity range. The solution viscosity and the reduced temperature T/Tg (Tg being the glass transition temperature) were varied by changing the sucrose concentration and the temperature of the system. The voltammetric limiting current obtained with a disk microelectrode and the i(t) response on a cylindrical microelectrode after a potential step were used to determine diffusion coefficients from 7 × 10-6 cm2 s-1 down to 2 × 10-11 cm2 s-1. The electrochemical procedure described in this work allows a simple and accurate measurement of the dynamics of electroactive solutes in glass-forming liquids.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis. We will look forword to the important role of 1273-86-5, and how the biochemistry of the body works.Recommanded Product: Ferrocenemethanol
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion