Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. Electric Literature of 1271-48-3. Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. Introducing a new discovery about 1271-48-3, Name is 1,1′-Ferrocenedicarboxaldehyde
The potential use of (aminomethyl)ferrocene and 1,1? -di(aminomethyl)ferrocene as precursor for Schiff base chemistry has been tested. (Aminomethyl)ferrocene reacts with 3,3? -(3-oxapentane-1,5-diyldioxy)bis(2-hydroxybenzaldehyde) to give the [2+1] diiminic ligand 8. 8 reacts with LaCl3 and Ni(CH3COO) 2 giving the corresponding complexes 9 and 10. 1,1? -Di(aminomethyl)ferrocene was prepared by conversion of 1,1? -di(formyl)ferrocene into 1,1?-di(formyl)ferrocene oxime, followed by reduction of the oxime with LiAlH4. Easy degradation of 1,1?-di(aminomethyl)ferrocene prevented its use as aminic precursor for the synthesis of Schiff base ligands. Isomerization occurred about the carbon-nitrogen double bonds of 1,1?-di(formyl)ferrocene oxime giving rise to three isomers. The X-ray analysis has shown that in the 5a complex three independent molecules having different conformation are present.
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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion