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In the presence of tetrabutylammonium hydroxide as catalyst and at room temperature, ethyl ferrocenecarboxylate, ethyl ferrocenylacetate, ethyl 3-ferrocenylpropanoate, 1,1?-ferrocenyl-bis(ethyl propanoate), ethyl 3-ferrocenylpropenoate and 1,1?-ferrocenyl-bis(ethyl propenoate) undergoes facile transesterification reaction with aliphatic, benzyl and allyl alcohols to furnish the corresponding ferrocenyl esters in good to excellent yields. Ring closing metathesis of the ester Fc-1,1?-(CHCH-CO2CH 2CHCH2)2 yields the corresponding closed loop ferrocenyl ester.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion