Related Products of 1273-86-5, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 1273-86-5, molcular formula is C11H3FeO, introducing its new discovery.
Synthesis and electrochemical properties of a series of ferrocene-containing alcohols
A series of primary ferrocenylalcohols, Fc-(CH2)m-OH with m = 1-4 and Fc = ferrocenyl, was synthesised by reduction of the appropriate ferrocenylcarboxylic acids, Fc-(CH2)n-COOH (n = 0-3) and the ester methyl 4-ferrocenylbutanoate with LiAlH4, the reduction of the gamma-ketoacid ferrocylpropanoic acid, Fc-CO-(CH 2)2-COOH, with AlCl3/LiAlH4, and the reduction of ferrocenylcarboxaldehyde, FcCHO, with NaBH4. The secondary ferrocenyl alcohols CpFe(C5H4-CH(OH)-CH 3) and Fe(C5H4-CH(OH)-CH3) 2 were obtained by NaBH4 reduction of acetyl and diacetyl ferrocene. The different reduction methods are compared. The electrochemistry of the alcohols was studied by cyclic voltammetry in CH3CN/0.1 M N(nBu)4PF6 utilising a platinum working electrode. The ferrocenyl group showed reversible electrochemistry with the formal reduction potential (Eo? versus Fc/Fc+) of the ferrocenyl group inversely proportional to side chain length. The influence of the side chain length on Eo? was more pronounced for the acids because the electron-withdrawing properties of the carbonyl group is stronger than that of the alcohol group. Ion pairing was found to play a major role in the electrochemical behaviour of ferrocenylmethanol, Fc-CH 2-OH.
Synthesis and electrochemical properties of a series of ferrocene-containing alcohols
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 1273-86-5 is helpful to your research. Related Products of 1273-86-5
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Iron Catalysis in Organic Synthesis | Chemical Reviews,
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