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Synthesis, characterization and third-order nonlinear optical properties of symmetrical ferrocenyl Schiff base materials
Six symmetrical ferrocenyl Schiff base materials were synthesized and characterized by UV, 1H NMR, mass spectrometry (MS) and elemental analysis. Their off-resonant third-order nonlinear optical properties were measured using femtosecond laser and degenerate four-wave mixing (DFWM) technique. The third-order nonlinear optical susceptibilities chi(3) were 1.961-6.363 ¡Á 10-13 esu. The nonlinear refractive indexes n2 were 3.609-11.716 ¡Á 10-12 esu. The second-order hyperpolarizabilities gamma of these molecules were 1.967-6.388 ¡Á 10-31 esu. The response time were 45.759-73.079 fs. The results indicate that these materials have potential nonlinear optical applications.
Synthesis, characterization and third-order nonlinear optical properties of symmetrical ferrocenyl Schiff base materials
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion