Chemistry is traditionally divided into organic and inorganic chemistry. Computed Properties of C12H10FeO2, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 1271-48-3
Mono and difunctionalisation of chiral ferrocenyl bis-acetals. X-Ray crystal structure of bis-1,1?-[(2S, 4S)-(hydroxymethyl)-2-dioxane1,3]-ferrocene
The chiral 1,1?-bis-acetals, bis-1,1?-[(2S, 4S)-(hydroxymethyl)-2-dioxane1,3]-ferrocene (3) and 1,1?-bis-1,1?-[(2S, 4S)-(methoxymethyl)-2-dioxane1,3]-ferrocene (4) were synthesized. (3) was crystallographically characterised. The ortholithiation of (4) was studied in various conditions. Fair yields of monosubstituted compounds could be obtained with a complete regioselectivity in favor of the 2 position but the diastereoselectivities were moderate (up to 35%). Some disubstituted compounds can be isolated but in low yields (up to 8%). The regioselectivity is complete in favor of the 2,2?-disubstituted isomer. Only the diastereoisomer with two opposite planar chiralities is observed.
Mono and difunctionalisation of chiral ferrocenyl bis-acetals. X-Ray crystal structure of bis-1,1?-[(2S, 4S)-(hydroxymethyl)-2-dioxane1,3]-ferrocene
If you are interested in 1271-48-3, you can contact me at any time and look forward to more communication. Computed Properties of C12H10FeO2
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion