In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Application In Synthesis of 1,1′-Dibenzoylferrocene, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 12180-80-2, name is 1,1′-Dibenzoylferrocene. In an article£¬Which mentioned a new discovery about 12180-80-2
Acyl-substituted ferrocenes as driers for solvent-borne alkyd paints
Ferrocenes bearing acyl substituents in the cyclopentadienyl rings [Fe(eta5-C5H4COR)(eta5-C 5H5)] and [Fe(eta5-C5H 4COR)2] (R = CH3, CF3 and Ph) were examined as new driers for solvent-borne alkyd binder. All studied ferrocenes were found to be active catalysts for cross-linking reaction of the alkyd. These iron(II) compounds give solid polymeric films with hardness and drying time comparable to the commercial cobalt(II) drier. Acetyl- and benzoyl-substituted ferrocenes show an excellent synergic effect with the cobalt drier giving hard polymeric films within short drying time. The kinetics of the alkyd autoxidation was followed by FTIR spectroscopy. Spin-trapping ESR technique has proven the important role of the ferrocenium cation upon decomposition of hydroperoxides by ferrocene-based driers. The peroxy and alkoxy radicals, appearing in drying process, were resolved by the new spin trap methyl-N-mesityl nitrone.
Acyl-substituted ferrocenes as driers for solvent-borne alkyd paints
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 12180-80-2, help many people in the next few years.Application In Synthesis of 1,1′-Dibenzoylferrocene
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion