Electric Literature of 1273-94-5, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction. 1273-94-5, Name is 1,1′-Diacetylferrocene, molecular weight is 262.0412. belongs to iron-catalyst compound, In an Article£¬once mentioned of 1273-94-5
Substituent effects in the iron 2p and carbon 1s edge Near-Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy of ferrocene compounds
The iron 2p and carbon 1s near-edge X-ray absorption fine structure (NEXAFS) spectra of substituted ferrocene compounds (Fe(Cp-(CH3) 5)2, Fe(Cp)(Cp-COOH), Fe(Cp-COOH)2, and Fe(Cp-COCH3)2) are reported and are interpreted with the aid of extended Hiickel molecular orbital (EHMO) theory and density functional theory (DFT). Significant substituent effects are observed in both the Fe 2p and C 1s NEXAFS spectra. These effects can be related to the electron donating/withdrawing properties of the cyclopentadienyl ligands and their substituents as well as the presence of pi* conjugation between the cyclopentadienyl ligand and unsaturated substituents.
Substituent effects in the iron 2p and carbon 1s edge Near-Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy of ferrocene compounds
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion