Chemistry is a science major with cience and engineering. The main research directions are preparation and modification of special coatings, and research on the structure and performance of functional materials. In a patent, 1271-51-8, name is Vinylferrocene, introducing its new discovery. Quality Control of Vinylferrocene
Two novel isoxazoline N,N-bidentate ligands with ferrocene backbone have been synthesized and employed for the palladium-catalyzed Heck coupling reaction. Among them, 1,3-bis-(5-ferrocenylisoxazoline-3-yl)benzene was found to be thermally stable and a highly effective ligand for Heck coupling reaction in neat water without N2 protection, affording the desired coupling products in good to excellent yield with high diastereoselectivity. The developed catalytic system was also well workable for 1,2-disubstituted alkenes, which were less involved in the Heck reaction for its larger steric hindrance. Copyright
Novel isoxazoline ligand with ferrocene backbone: Preparation and application in Heck reaction with water as solvent
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Quality Control of Vinylferrocene, you can also check out more blogs about1271-51-8
Reference:
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