Chemistry is a science major with cience and engineering. The main research directions are preparation and modification of special coatings, and research on the structure and performance of functional materials. In a patent, 1273-86-5, name is Ferrocenemethanol, introducing its new discovery. Computed Properties of C11H3FeO
This paper describes an electrochemically mediated enzyme reaction of polyethyleneglycol (PEG)-modified galactose oxidase (GAO) in organic solvents as well as in an aqueous solution. Catalytic currents were investigated in the presence of ferrocene derivatives as mediators and PEG-modified GAO in several organic solvents. The catalytic current due to the mediated enzyme reaction was obtained in acetonitrile, N,N-dimethylformamide, N,N-dimethylacetamide and dimethylsulfoxide (DMSO). Stability tests of PEG-modified GAO in organic solvents demonstrated that the initial Ik/Id value was highest in acetonitrile; however, it gradually decreased. The PEG-modified GAO was more stable in DMSO. Reactivities of several mediators were investigated. Although a positively charged mediator indicated high reactivity in the aqueous solution, non-charged mediators such as ferrocene dimethanol and n-butyl ferrocene showed the highest activity in organic solvents. Substrate specificity demonstrated that the catalytic activity for benzyl alcohol in acetonitrile was greater than in aqueous solution. The effect of water content in acetonitrile was investigated. The catalytic activity decreased with the increase in water content.
Electrochemically mediated enzyme reaction of polyethyleneglycol-modified galactose oxidase in organic solvents
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Computed Properties of C11H3FeO, you can also check out more blogs about1273-86-5
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion