While the job of a research scientist varies, most chemistry careers in research are based in laboratories,Recommanded Product: 1,1′-Ferrocenedicarboxaldehyde, where research is conducted by teams following scientific methods and standards. In a patent,Which mentioned a new discovery about 1271-48-3
Homogeneous catalysis has been responsible for many major recent developments in synthetic organic chemistry. The combined use of organometallic and coordination chemistry has produced a number of new and powerful synthetic methods for important classes of compounds in general and for optically active substances in particular. For this aim, a new class of chiral modular C2-symmetric ferrocenyl phosphinite ligands has been prepared in good yields by using the inexpensive 1,1?-ferrocenedicarboxyaldehyde and various ferrocene based-amino alcohols as starting materials, and applied in the rhodium(I)-catalyzed asymmetric transfer hydrogenation (ATH) of aromatic ketones to give corresponding secondary alcohols with excellent enantioselectivities and reactivities using isoPrOH as the hydrogen source (up to 99% conversion and 99% ee). The substituents on the backbone of the ligands are found to exhibit a remarkable effect on both the activity and % ee. The structures of these ligands and their complexes have been elucidated by a combination of multinuclear NMR spectroscopy, IR spectroscopy and elemental analysis.
You can also check out more blogs about1273-86-5 and wish help many people in the next few years. .Recommanded Product: 1,1′-Ferrocenedicarboxaldehyde
Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion