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The character of intramolecular hydrogen bonds in ferrocenyl- and nonamethylferrocenylcarbinols has been determined from their IR spectra and on the basis of molecular mechanics calculations.The intramolecular hydrogen bonds of the OH…Fe type are formed when the steric requirements of the substituents at the carbinol carbon atom and Cp rings make the corresponding conformations energetically favourable.The correlation of proton-donating ability of the ferrocenyl- and nonamethylferrocenylcarbinols relative to the stability of intramolecular hydrogen bonds is discussed.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion