Our Top Choice Compound: Vinylferrocene

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The reaction of tris(3-iodopentane-2,4-dionato)cobalt(III) with vinylferrocene in the presence of triphenylphosphine and a catalytic amount of PdII produced two structural isomers.The characterisation of these isomers, 2- and 3-ferrocenyl-4-acetyl-2,3-dihydro-5-methylfuran <(B) and (C), respectively> is described.Their structures have been determined by single-crystal X-ray diffractometry: (B) is orthorhombic, space group Pbca with a=9.821(2), b=10.414(4), c=27.761(6) Angstroem, final R=0.031, R’=0.050 for 1706 reflections; (C) is monoclinic, space group is P21/c with a=9.692(1), b=7.678(5), c=19.082(3) Angstroem, final R=0.031, R’=0.048 for 1641 reflections.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion