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A new heterocyclic ferrocene derivative, 1,1′-diacetylferrocenebis(5-phenyl-1,3-oxazol-2-ylcarbonyl)hydrazone (H2Dfoh) and its coordination complexes, [M2(Dfoh)·(OAc)2]·nH2O [(M = Cu(II), Ni(II), Co(II), Cd(II), Pb(II), Mn(II)], were prepared by reacting H2Dfoh with the metal acetates and were characterized by elemental analyses, molar conductivities, IR, 1H NMR, UV spectra and thermal analyses. H2Dfoh appears to act as a bidentate ligand, coordinating to two metal atoms through the azomethine nitrogen and enolic oxygen atoms. OAc- coordinates to the metals as a symmetric bidentate ligand.
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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion