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This paper describes the preparation of a variety of 1?-substituted iodoferrocenes from 1-iodo-1?-(tri-n-butyltin)ferrocene by an electrophilic substitution of the tri-n-butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Application of 1271-51-8, You can get involved in discussing the latest developments in this exciting area about 1271-51-8
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion