As a common heterocyclic compound, it belongs to iron-catalyst compound, name is Acetylferrocene, and cas is 1271-55-2, its synthesis route is as follows.,1271-55-2
To a 500 mL three-necked flask equipped with a mechanical stirrer and a spherical condenser were added 0.01 mol of acetyl ferrocene,0.1 mol morpholine,0.05 mol of sulfur and 0.001 mol of Na2S ¡¤ 9H2O, Oil bath was heated to 128 deg C, Reflux 7h, TLC monitoring.The reaction is completed,The mixture was cooled to room temperature,Then, 10 mL of ethanol and 25 mL of 2 mol / L sodium hydroxide aqueous solution were added thereto,Stirring temperature,Reflux 4h,TLC monitoring.The reaction is completed,cool down,Adjust the pH value with hydrochloric acid to between 7 and 8,Filter cleaning,The filtrate was then adjusted to pH 1 with hydrochloric acid,Placed overnight,filter,Washed,A yellow-brown solid,Namely ferrocenyl acetic acid,The yield is 79%.
With the complex challenges of chemical substances, we look forward to future research findings about Acetylferrocene
Reference£º
Patent; Shaanxi University of Science and Technology; Liu, Yuting; Song, Simeng; Yin, Dawei; Jiang, Shanshan; Liu, Beibei; Yang, Aning; Wang, Jinyu; Lyu, Bo; (13 pag.)CN104231004; (2017); B;,
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