Can You Really Do Chemisty Experiments About 1273-86-5

Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 1273-86-5, Name is Ferrocenemethanol. In a document type is Article, introducing its new discovery., 1273-86-5

Synthese und Reaktivitaet von Ferrocenyl-Pentacarbonylmangan, Mn(CO)5Fc

The compound Mn(CO)5Fc can be prepared by the reaction of Mn(CO)5Br with ferrocenyllithium, FcLi.The mangana-beta-diketone H, obtained as a side-product, is converted into Mn(CO)5Fc with concomitant formation of diferrocenoyl, (FcCO)2.In proton-containing solvents the ferrocenyl group of Mn(CO)5Fc is slowly split off in the form of ferrocenylcarbonyl compounds: the aldehyde Fc-CHO is formed in acetonitrile, and the ester Fc-COOCH3 in methanol.The ferrocenyl-manganese complex, Mn(CO)5Fc, reacts with triphenylphosphane to give cis-Mn(CO)4(PPh3)Fc, with t-butylisocyanide to give fac-Mn(CO)3(CNtBu)2COFc, and with oxidants such as NOBF4 or iodine to give the ferricenium cation +.

Synthese und Reaktivitaet von Ferrocenyl-Pentacarbonylmangan, Mn(CO)5Fc

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion