Category: 14024-18-1

Iron(III) acetylacetonate, cas is 14024-18-1, it is a common heterocyclic compound, the iron-catalyst compound, its synthesis route is as follows.

The synthesis of Fe3O4 NPs refers to the previousmethod.19 18 1,2-hexadecanediol (10 mM), Fe(acac)3(2 mM), oleicacid (6 mM) and oleylamine (6 mM) wereadded into 20 mL of diphenyl ether, and stirred vigorouslyunder the protection of nitrogen. The mixture wereheated at 473 K for 45 min, then refluxed under the protectionof nitrogen at 538 K for 120 min to prepare thegrey-black mixture. After cooled down to the room temperature,60 mL of ethanol was added, the raw productswere collected by centrifugation, and then dispersed into10 mL of n-hexane. The ethanol (60 mL) was added, followedby centrifugation, and the procedure was repeatedfor 8-10 times in order to clean thoroughly. Finally, the5-nm Fe3O4 nanoparticles were synthesized and preservedin n-hexane.

14024-18-1, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,14024-18-1 ,Iron(III) acetylacetonate, other downstream synthetic routes, hurry up and to see

Reference：
Article; Gan, Qi; Zhu, Jiaoyang; Yuan, Yuan; Liu, Changsheng; Journal of Nanoscience and Nanotechnology; vol. 16; 6; (2016); p. 5470 – 5479;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

As a common heterocyclic compound, it belongs to iron-catalyst compound, name is Iron(III) acetylacetonate, and cas is 14024-18-1, its synthesis route is as follows.

General procedure: Sample preparation was performed similar to the procedure given in our previous report [15]. Oxide precursors (Fe1-xAlx)3O4 were prepared from a mixture of Fe(acac)3 and Al(acac)3 in an autoclave at 473K for 48h.

14024-18-1, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,14024-18-1 ,Iron(III) acetylacetonate, other downstream synthetic routes, hurry up and to see

Reference：
Article; Matsumoto, Yoshiyuki; Masubuchi, Yuji; Nakazawa, Yoshiyuki; Itami, Hitoshi; Tsuchiya, Masayuki; Kikkawa, Shinichi; Journal of Alloys and Compounds; vol. 789; (2019); p. 697 – 703;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

Name is Iron(III) acetylacetonate, as a common heterocyclic compound, it belongs to iron-catalyst compound, and cas is 14024-18-1, its synthesis route is as follows.

General procedure: A solvothermal method was implemented to prepare CuFe2O4and Fe3O4 NPs. For the synthesis of Fe3O4 NPs, 4 mmol of Fe(acac)3 and 40 ml of triethylene glycol were mixed in a 200 ml round bottom flask connected to a reflux condenser. To homogenize thesolution, the temperature was increased to 100 C and maintainedat this temperature for 1 h. Afterwards the obtained homogenoussolutionwas transferred to a Teflon lined autoclave (75 ml capacity)and then placed in a furnace at 260 C for 24 h. Next, the mixturewas left to cool down to room temperature, which resulted in a black homogeneous dispersion containing magnetite nanoparticles.The obtained product was washed with acetone severaltimes using centrifugation. Then, the nanoparticles were put to dryin an oven at 50 C for 12 h. For the synthesis of CuFe2O4 NPs, thesame procedure was employed except that the stoichiometricamount of Cu(acac)2 was added to the triethylene glycol at the firstof synthesis process. Briefly, the synthesis process is schematicallyshown in Fig. 1.

14024-18-1, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,14024-18-1 ,Iron(III) acetylacetonate, other downstream synthetic routes, hurry up and to see

Reference：
Article; Fotukian, Seyedeh Maryam; Barati, Aboulfazl; Soleymani, Meysam; Alizadeh, Ali Mohammad; Journal of Alloys and Compounds; vol. 816; (2020);,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

14024-18-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Iron(III) acetylacetonate, cas is 14024-18-1,the iron-catalyst compound, it is a common compound, a new synthetic route is introduced below.

Fe(acac)3 (3 mmol) was dissolved in 20 ml of oleylamine and 5 ml of n-hexane. The reaction mixture was thoroughly stirred under N2 atmosphere for 30 min in a 50 ml Teflon-lined stainless steel autoclave that was carefully sealed. The autoclave was heated in a furnace at 190 C for 8 h under autogenous pressure. The resulting dark suspensions were extracted by adding 50 ml of ethanol followed by centrifugation. After washing the precipitates three times with ethanol, uniform Fe3O4 NPs were formed. These NPs were redispersed into n-hexane and a black-brown n-hexane dispersion of Fe3O4 NPs was thus obtained. Thus, the Fe3O4 suspension was transferred to 100 ml volumetric flask, evenly mixed with n-hexane for measurement of concentration of Fe3O4 through the 1,10-phenanthroline monohydrate dyeing method using UV-Vis spectrophotometer. Similar procedures for the preparation of Fe3O4 NPs were carried out at different conditions, including different reaction temperatures, times, and solvents. The solvothermal temperatures for samples S1 and S3 differed from that for S2. For samples S4-S6, the reaction times differed from that of S2. For samples S7-S9, the content of n-hexane differed from that of sample S2. The detailed preparation conditions are listed in Table 1 .

Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of Iron(III) acetylacetonate, 14024-18-1

Reference：
Article; Liu, Jing; Wang, Lu; Wang, Jing; Zhang, Lantong; Materials Research Bulletin; vol. 48; 2; (2013); p. 416 – 421;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

As a common heterocyclic compound, it belongs to iron-catalyst compound, name is Iron(III) acetylacetonate, and cas is 14024-18-1, its synthesis route is as follows.

Fe3O4 nanoparticles were prepared by high temperature diolthermal decomposition method. Briefly, 0.5 g Fe(acac)3 and 100 mL benzyl alcohol were added into a flask. The mixture was heated to 200 C and maintained for 2 h. After the flask cooled down, the obtained black precipitations were collected with the help of a magnet and washed thoroughly with ethanol several times. The black product was Fe3O4 nanoparticles.

14024-18-1, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,14024-18-1 ,Iron(III) acetylacetonate, other downstream synthetic routes, hurry up and to see

Reference：
Article; Liu, Rui; Mi, Shu; Li, Yuanyuan; Chen, Cong; Xie, Yong; Chen, Qiang; Chen, Ziyu; Science China Chemistry; vol. 59; 4; (2016); p. 394 – 397;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

14024-18-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Iron(III) acetylacetonate, cas is 14024-18-1,the iron-catalyst compound, it is a common compound, a new synthetic route is introduced below.

Synthesis of Iron Oxide Nanoparticles [0098] Particles were prepared via a modified method first presented by Sun and Zeng (J. Am. Chem. Soc., 2002, 124, 8204-8205). Briefly, magnetite particles were produced by adding iron(III) acetylacetonate (Fe(acac)3, 0.35 g, 1 mmol) and oleylamine (OAm, 2.5 mL, 17.09 mmol) in 17.5 mL of benzyl ether to a round bottom flask under a nitrogen blanket. The solution was then heated at 3 C. per minute to 300 C. and held isothermally for 1 hour. The particles were purified by repeated washing with ethanol and centrifugation.

The chemical industry reduces the impact on the environment during synthesis,14024-18-1,Iron(III) acetylacetonate,I believe this compound will play a more active role in future production and life.

Reference：
Patent; Clemson University; McNealy, Tamara L.; Mefford, IV, Olin Thompson; Saville, Steven L.; US2014/93550; (2014); A1;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

14024-18-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Iron(III) acetylacetonate, cas is 14024-18-1,the iron-catalyst compound, it is a common compound, a new synthetic route is introduced below.

A typical procedure for preparation of oil-soluble magnetite nanoparticles is briefly described as follows: first, 20 mL of diethylene glycol, 0.70 g (2 mmol) of iron (III) acetylacetonate, and 1.06 mL (3 mmol) of oleic acid were mixed in a 50 mL Teflon-lined stainless autoclave while magnetically stirring. Then, the autoclave was put into oven, kept at 180C for 5 h. After cooled to room temperature naturally, 40 mL ethanol was added to yield a black precipitate. The black Fe3O4 precipitate was separated by centrifuging at 10,000 rpm for 20 min, and re-dispersed in 10 mL of hexane or dried at 60C under vacuum for 24 h. (The as-prepared product was donated as SO1.) The as-synthesized Fe3O4 colloid in hexane is hydrophobic and stable for nearly a year, while the dried Fe3O4 sample can be stable for several months. The synthesis of water-soluble magnetite nanoparticles was carried out only by reacting an iron precursor, iron (III) acetylacetonate (Fe(acac)3), in the polyol medium (diethylene glycol) without oleic acid under the same reaction conditions. After cooling down to room temperature, 40 mL of ethyl acetate was added to the reaction solution resulted in a black precipitation of magnetite nanoparticles which was then separated from the solution by centrifuging at 10,000 rpm for 20 min. After washed with ethyl acetate for three times, the precipitation was re-dispersed in polar solvents such as ethanol and water for further investigation. The Fe3O4 solid productions could also be obtained by drying the precipitation at 60C under vacuum for 24 h. (The as-prepared product was donated as SW1.)

Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of Iron(III) acetylacetonate, 14024-18-1

Reference：
Article; Chen, Fenghua; Zhao, Taonan; Chen, Qingtao; Han, Lifeng; Fang, Shaoming; Chen, Zhijun; Materials Research Bulletin; vol. 48; 10; (2013); p. 4093 – 4099;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

14024-18-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Iron(III) acetylacetonate, cas is 14024-18-1,the iron-catalyst compound, it is a common compound, a new synthetic route is introduced below.

Monodispersed Fe3O4 nanoparticles having a mean diameter of 8 nm were synthesized following the seed-growth method described by Sun et al. (J. Am. Chem. Soc., 2004, 126, 273-279). To that end, 6 nm Fe3O4 seeds were synthesized by mixing Fe(acac)3 (2 mmol), 1,2-hexadecanediol (10 mmol), oleic acid (6 mmol), oleylamine (6 mmol), and benzyl ether (20 mL) under nitrogen flow. The mixture was heated at 200 C. for 2 hours and was then kept under reflux (300 C.) for 1 hour. The solution was cooled to room temperature and was then washed with methanol to remove the solvent and to finally be redispersed in hexane. The 6 nm nanoparticles to produce 8 nm nanoparticles were re-grown as indicated above and by adding 84 mg of 6 nm nanoparticles dispersed in hexane.

The chemical industry reduces the impact on the environment during synthesis,14024-18-1,Iron(III) acetylacetonate,I believe this compound will play a more active role in future production and life.

Reference£º
Patent; Nanoimmunotech SRL; Universidad de Zaragoza; Fundacion Agencia Aragonesa Para la Investigacion y el Desarollo; Del Pino Gonzalez de la Higuera, Pablo Alfonso; Martinez de la Fuente, Jesus; Sanchez Espinel, Christian; Santos Martinez de Laguna, Ruben; US2014/275509; (2014); A1;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

As a common heterocyclic compound, it belongs to iron-catalyst compound, name is Iron(III) acetylacetonate, and cas is 14024-18-1, its synthesis route is as follows.

The magnetic iron oxide oxide nanoparticles [Fe-nanoparticles] were prepared as described [64-66]. In brief, the iron oleate complex was synthesized from 2mmol iron(III)acetyl acetonate [Fe(acac)3] that was suspended in 20mL of benzyl ether. After addition of 10mmol 1,2-hexadecanediol, 6mmol oleic acid and finally 6mmol oleylamine the reaction was started under argon atmosphere and heated to 250C under reflux for 30min. The resulting dark-brown solution was cooled to room temperature; during this process the magnetite nanoparticles are produced; they have a size of ?7nm, are monodisperse, and can be conveniently attracted as well as translocated in the organic as well as the aqueous environment by using a circular magnet 18¡Á10mm.

14024-18-1, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,14024-18-1 ,Iron(III) acetylacetonate, other downstream synthetic routes, hurry up and to see

Reference£º
Article; Li, Qiang; Wang, Xiaohong; Korzhev, Michael; Schroeder, Heinz C.; Link, Thorben; Tahir, Muhammad Nawaz; Diehl-Seifert, Baerbel; Mueller, Werner E.G.; Biochimica et Biophysica Acta – General Subjects; vol. 1850; 1; (2015); p. 118 – 128;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

14024-18-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Iron(III) acetylacetonate, cas is 14024-18-1,the iron-catalyst compound, it is a common compound, a new synthetic route is introduced below.

Nanosized Fe2O3 was synthesized by the thermolysisof an iron-containing precursor in a dispersion medium. Iron acetylacetonate prepared as describedin [7] was used as a precursor; the dispersion medium was diphenyl ether (DPE). The choice of DPE wasbased on the thermal stability, high boiling point (259C), and low toxicity of this material. Iron acetylacetonate(0.5 g) was dissolved in 10 mL of DPE;40 mL of DPE in a two-necked round-bottom flaske quipped with a reflux condenser was heated in an oil bath to 200C under vigorous stirring with a magnetic stirrer. After that, using a syringe, the iron acetylacetonate solution was rapidly introduced into hot DPE. The resulting mixture was held under vigorous stirring for 2 h to provide the completion of thermolysis and the formation of iron oxide particles; after that, the mixture was cooled and analyzed. To study the features of reduction of Fe2O3 and the chemisorption processes involving it, DPE was removed by vacuum distillation; the resulting material was a black powder.

The chemical industry reduces the impact on the environment during synthesis,14024-18-1,Iron(III) acetylacetonate,I believe this compound will play a more active role in future production and life.

Reference£º
Article; Lyadov; Kochubeev; Markova; Parenago; Khadzhiev; Petroleum Chemistry; vol. 56; 12; (2016); p. 1134 – 1139; Neftekhimiya; vol. 1; 2; (2016); p. 129 – 135,7;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion