We very much hope you enjoy reading the articles and that you will join us to present your own research about 1293-65-8, you can contact me at any time and look forward to more communication. Recommanded Product: 1,1′-Dibromoferrocene
Chemical research careers are more diverse than they might first appear, Recommanded Product: 1,1′-Dibromoferrocene, as there are many different reasons to conduct research and many possible environments. In a article, mentioned the application of 1293-65-8, Name is 1,1′-Dibromoferrocene, molecular formula is C10Br2Fe
Isomeric phosphinoferrocene ligands, viz. 1?-(diphenylphosphino)-1-cyanoferrocene (1) and 1?-(diphenylphosphino)-1-isocyanoferrocene (2), show markedly different coordination behaviours. For instance, the reactions of 1 with [PdCl2(MeCN)2] and [(LNC)Pd(mu-Cl)]2 (LNC = [2-(dimethylamino-kappaN)methyl]phenyl-kappaC1) produced the ?phosphine? complexes [PdCl2(1-kappaP)2] (7) and [(LNC)PdCl(1-kappaP)] (8), and the latter was converted into the coordination polymer [(LNC)Pd(mu(P,N)-1)][SbF6] (9). Conversely, the reaction of 2 with [(LNC)Pd(mu-Cl)]2 involved coordination of the phosphine moiety and simultaneous insertion of the isocyanide group into the Pd-C bond, giving rise to the P,eta1-imidoyl complex [PdCl(Ph2PfcN?CC6H4CH2NMe2-kappa3C,N,P)] (10; fc = ferrocene-1,1?-diyl). Compound 10 was further transformed into the Fischer carbene [PdCl(Ph2PfcN(Me)CC6H4CH2NMe2-kappa3P,C,N)][BF4] (11) by methylation with [Me3O][BF4]. The reactions of 2 with Pd-Me and Pd(eta3-allyl) precursors also led to imidoyl complexes [Pd(mu-Cl)(Ph2PfcN?CR-kappa2C,P)]2 (R = Me: 12, R = allyl: 15), which were cleaved with PPh3 into the corresponding monopalladium complexes [PdCl(PPh3)(Ph2PfcN?CR-kappa2C,P)] (R = Me: 13, R = allyl: 16). The treatment of 12 and 15 with thallium(i) acetylacetonate (acac) produced [Pd(acac-O,O?)(Ph2PfcN?CR-kappa2C,P)] (R = Me: 17, R = allyl: 18). Through proton transfer, these complexes reacted with Ph2PCH2CO2H, ultimately producing bis-chelate complexes [Pd(Ph2PCH2CO2-kappa2O,P)(Ph2PfcN?CR)] (R = Me: 19, R = prop-1-enyl (sic!): 20). In addition, compound 13 was converted into the P-chelated carbene [PdCl(PPh3)(Ph2PfcN(Me)CMe-kappa2C,P)][BF4] (14). Compounds 10, 11, 13 and 14 were studied by cyclic voltammetry and by DFT computations.
We very much hope you enjoy reading the articles and that you will join us to present your own research about 1293-65-8, you can contact me at any time and look forward to more communication. Recommanded Product: 1,1′-Dibromoferrocene
Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion