Tag: 1271-55-2

1271-55-2, Acetylferrocene is a iron-catalyst compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

General procedure: To a magnetic stirred solution of acylferrocene (10 mmol) in methanol (30 mL) tosylhydrazine (10 mmol) was added. Then the mixture was stirred vigorously at 70 C. TLC analysis was performed until the spot of acylferrocene disappeared. Then the solution was cooled to room temperature, and N-tosylhydrazone precipitated. The precipitate was filtered and washed with petroleum ether (10 mL * 2) to get the pure product.

1271-55-2, 1271-55-2 Acetylferrocene 79159, airon-catalyst compound, is more and more widely used in various.

Reference£º
Article; Liu, Yueqiang; Ma, Xiaowei; Liu, Yan; Liu, Ping; Dai, Bin; Synthetic Communications; vol. 48; 8; (2018); p. 921 – 928;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

1271-55-2, Acetylferrocene is a iron-catalyst compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

General procedure: To a solution of acetyl ferrocene (0.34 g, 2.5 mmol) and correspondingactive aldehyde (2.5 mmol) in dry ethanol (20 ml) takenin a beaker (100 ml), a catalytic quantity of potassium hydroxide(0.05 g, 1.25 mmol)was added and the reaction mixturewas heatedinside a microwave oven for 54e68 s (at 210W, i.e. ~30% microwavepower) [25]. After complete the reaction mixture was cooled in anice bath and the product thus formed were filtered, washed withethanol followed by washing with water till the washings wereneutral and recrystallized from distilled ethanol and chloroform(Scheme 1 and Table 1).

The synthetic route of 1271-55-2 has been constantly updated, and we look forward to future research findings.

Reference£º
Article; Khan, Salman A.; Asiri, Abdullah M.; Al-Ghamdi, Najat Saeed M.; Zayed, Mohie E.M.; Sharma, Kamlesh; Parveen, Humaira; Journal of Molecular Structure; vol. 1139; (2017); p. 137 – 148;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.1271-55-2,Acetylferrocene,as a common compound, the synthetic route is as follows.

General procedure: To a solution of acetyl ferrocene (228 mg, 1mmol) in ethyl alcohol (15 ml) was added KOH (110 mg, 2 mmol) and stirred at room temperature for 15 min, then appropriate aromatic aldehyde (1 mmol) in ethyl alcohol (5 ml) was slowly added and the mixture was allowed to stirred at room temperature. After complete consumption of acetyl ferrocene (monitored by TLC, a red to purple colour solid was formed), 2-hydrazinobenzothiazole (165 mg, 1.0 mmol), KOH (110 mg, 2 mmol) and additional ethyl alcohol (5 ml) and was slowly added and the resulting mixture was refluxed for overnight. After completion of the reaction (monitored by TLC, an orange to red colour solid was formed), the reaction mixture was cooled, the solid formed was filtered, washed with cold ethanol-water mixture, water and air dried. The resulting solid was purified by column chromatography using n-hexane/ethyl acetate mixture (9:1 to 8:2) to obtain the ferrocene derivative.

The synthetic route of 1271-55-2 has been constantly updated, and we look forward to future research findings.

Reference£º
Article; Kiran Kumar, Chakka; Trivedi, Rajiv; Giribabu, Lingamallu; Niveditha, Surukonti; Bhanuprakash, Kotamarthi; Sridhar, Balasubramanian; Journal of Organometallic Chemistry; vol. 780; (2015); p. 20 – 29;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion