M.W:1000-2000 | - Iron catalyst

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12582-61-5, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,12582-61-5 ,Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer, other downstream synthetic routes, hurry up and to see

Name is Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer, as a common heterocyclic compound, it belongs to iron-catalyst compound, and cas is 12582-61-5, its synthesis route is as follows.

General procedure: To a CH2Cl2 solution (15 mL) of [(TPP)Fe]2(mu-O) (0.033 g, 0.024 mmol) was added trichloroacetic acid (0.010 g, 0.06 mmol). The mixture was stirred for 45 min, during which time the color of the solution changed from green to brown. The solvent was reduced to ?3 mL and hexane (10 mL) was added. The solution was slowly concentrated under reduced pressure until precipitation of the product occurred. The dark brown precipitate was collected by filtration, washed with hexane (2 × 15 mL), and dried in vacuo to give (TPP)Fe(OC(=O)CCl3) (0.020 g, 0.024 mmol, 50% isolated yield).

Reference：
Article; Xu, Nan; Yan, Beiqi; Awasabisah, Dennis; Powell, Douglas R.; Richter-Addo, George B.; Inorganica Chimica Acta; vol. 469; (2018); p. 183 – 188;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

Downstream synthetic route of Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer

It is a common heterocyclic compound, the iron-catalyst compound, Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer, cas is 12582-61-5 its synthesis route is as follows.

To a CH2Cl2 solution (15 mL) of [(TPP)Fe]2(mu-O) (0.033 g, 0.024 mmol) was added trichloroacetic acid (0.010 g, 0.06 mmol). The mixture was stirred for 45 min, during which time the color of the solution changed from green to brown. The solvent was reduced to ?3 mL and hexane (10 mL) was added. The solution was slowly concentrated under reduced pressure until precipitation of the product occurred. The dark brown precipitate was collected by filtration, washed with hexane (2 ¡Á 15 mL), and dried in vacuo to give (TPP)Fe(OC(=O)CCl3) (0.020 g, 0.024 mmol, 50% isolated yield). Slow evaporation of a CH2Cl2/cyclohexane (1:1 ratio; 4 mL) solution of the product at room temperature gave suitable crystals for X-ray diffraction studies. IR (CH2Cl2, cm-1): upsilonOCO(asym) = 1704. IR (KBr, cm-1): upsilonOCO(asym) = 1709. UV-vis (lambda (relative epsilon, mM-1cm-1), 2 ¡Á 10-5 M in CH2Cl2): 411 (138), 509 (14), 571 (8), 681 (4) nm.

Reference£º
Article; Xu, Nan; Yan, Beiqi; Awasabisah, Dennis; Powell, Douglas R.; Richter-Addo, George B.; Inorganica Chimica Acta; vol. 469; (2018); p. 183 – 188;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

Share a compound : 12582-61-5

With the rapid development of chemical substances, we look forward to future research findings about Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer

Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer, cas is 12582-61-5, it is a common heterocyclic compound, the iron-catalyst compound, its synthesis route is as follows.,12582-61-5

General procedure: To a CH2Cl2 solution (15 mL) of [(TPP)Fe]2(mu-O) (0.033 g, 0.024 mmol) was added trichloroacetic acid (0.010 g, 0.06 mmol). The mixture was stirred for 45 min, during which time the color of the solution changed from green to brown. The solvent was reduced to ?3 mL and hexane (10 mL) was added. The solution was slowly concentrated under reduced pressure until precipitation of the product occurred. The dark brown precipitate was collected by filtration, washed with hexane (2 ¡Á 15 mL), and dried in vacuo to give (TPP)Fe(OC(=O)CCl3) (0.020 g, 0.024 mmol, 50% isolated yield).

With the rapid development of chemical substances, we look forward to future research findings about Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer

Brief introduction of 12582-61-5

The synthetic route of 12582-61-5 has been constantly updated, and we look forward to future research findings.

12582-61-5, Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer is a iron-catalyst compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated,12582-61-5

General procedure: To a CH2Cl2 solution (15 mL) of [(TPP)Fe]2(mu-O) (0.033 g, 0.024 mmol) was added trichloroacetic acid (0.010 g, 0.06 mmol). The mixture was stirred for 45 min, during which time the color of the solution changed from green to brown. The solvent was reduced to ?3 mL and hexane (10 mL) was added. The solution was slowly concentrated under reduced pressure until precipitation of the product occurred. The dark brown precipitate was collected by filtration, washed with hexane (2 ¡Á 15 mL), and dried in vacuo to give (TPP)Fe(OC(=O)CCl3) (0.020 g, 0.024 mmol, 50% isolated yield).

The synthetic route of 12582-61-5 has been constantly updated, and we look forward to future research findings.